SCPs are a ceiling, never a grant
An SCP sets the maximum permissions available anywhere in its scope. An explicit IAM allow can never exceed it, so an SCP deny beats a local allow - which is the usual explanation when a developer is refused an action their own policy permits. That makes the SCP the right tool wherever enforcement must survive a local administrator: denying LeaveOrganization, restricting Regions, requiring a permissions boundary on role creation, or an allow-list that permits only approved services and denies the rest by default. Attached at a parent OU or the root, it is inherited by anything created beneath, so a new OU is covered without anyone remembering a step.